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Forum Index : Solar : Li -ion battery

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bob.steel
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Joined: 27/02/2020
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Posted: 01:52am 09 Feb 2022
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  Godoh said  Hi Bob, my experience of Lithium batteries is limited to my computer and phone batteries, plus what I have seen on other sites of people buying Lithium cells ( individual) and wiring them themselves to make batteries for their solar systems.
Most ones I have seen have been wired to BMS setups with lots of small wires monitoring each cell.
With the quality of components coming out these days, I am loathe to trust electronics that are built into a non repairable position, they may last the life of the batteries but then again they may not. I like to fix things where possible.
Where I live in Tasmania ( small island off the bottom of Australia) LIFEpo4 batteries are only just appearing in battery shops. I have seen 12 volt batteries which must have BMS systems built in, They seemed very expensive to me. A 200 amp hour high quality battery is nearly $1600 here.
Works out more expensive for me and I would have had to have 3 parallel banks to get the capacity I have. Plus cost me about $2500 more.
Freight here can be a killer. Buying in batteries from the mainland as we call it, can be very expensive.
I prefer not to parallel batteries myself. That is just my preference.
LifePo4 batteries may be great but then there are so many new battery types being trialed and touted that I preferred to spend my money on something that I know will work. I expect that with good care I should get 12 to 15 years out of the batteries I have, after they expire I will look at what is available.
I may be behind the times but I prefer what has worked for me.
My last battery bank was a set of ex telecom batteries that were given to me, they were 15 years old when I was given them and we got another 5 years out of them before we bought a brand new bank of BAE batteries.
To me it is interesting to see new things that come along and to see what people are doing.
cheers
Pete

Yep I can see your points .To each his own but its said if you get more than 3 years from Lead acid you are not using them. Not much I disagree with except the sealed in plastic cases can be opened . Before I bought my latest acquisitions I pulled a big one apart to have a look

Here is an old one that I resurected . It had dendrites and one cell shorted . If you know what you are doing you can get them back up and charging . Its about 8 years old now and still shows 90% capacity.


There are LTO cells on the market with massive charge and discharge rates but they are too exxy for me. These are cheap . Cheaper than lead acid now.
Edited 2022-02-09 11:56 by bob.steel
 
Revlac

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Posted: 03:11am 09 Feb 2022
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Have seen a few (drop in replacement lithium forklift batteries for sale, don't know who is using them.


  Quote  My last battery bank was a set of ex telecom batteries that were given to me, they were 15 years old

@Godoh
What type and brand where those telecom batteries?  The might be the same as the ones I had. They where barely usable at 15 years old, many where failing, all where stuffed at 20 years.
Cheers Aaron
Off The Grid
 
Godoh
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Posted: 03:28am 09 Feb 2022
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Hi Aaron, I don't remember the brand, they were clear plastic cases, 200 amp hour each from memory. I was give about 40 of them , so just checked each out, got rid of the ones that had corroded terminals, or did not have good hydrometer readings and used the rest.
Some failed over the 5 years I had them but then, I paid nothing for them so it did not matter to me.
I have always been pretty minimalist with my stuff. I have always preferred a life/work balance that was heavily weighed on the life side. So have never had enough money before to buy really good quality batteries.
Retirement came and enough money to have a good system. Plus panels got really cheap compared to decades ago.
So most of my panels are second hand, the batteries are new, new regulators and home made inverters.
So far the 8010 based inverters I have put together are doing a great job.
A few modifications to the actual 8010 boards that were guided by helpful folk here and on anotherpower site. And a reliable system is there.
As you say the telecom batteries were stuffed after 20 years but then the scrap dealers gave me a good price for them.
I am hoping that as I am 66 now that the BAE batteries will do me until I am nearly 80, if I am still hanging about this mad and getting madder planet by then.
Cheers
Pete
 
noneyabussiness
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Posted: 07:10am 09 Feb 2022
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" To each his own but its said if you get more than 3 years from Lead acid you are not using them. "

its comments like this that really peeve me off, one of the forklift batteries Im using is 3 and a half years old, as good as the day i recieved it, I pull a minimum 30 % out of it every night ( common to use 40-50) how is that " not using it " ?? I have nothing against li-ion , but some people are so worried about going off grid because of myths like this, that they need to spends BIG dollars on the latest tech just to get some imaginary time / cycle life , because if its not x brand / type you won't get the cycles / life out of it... which is simply not true... I do totally agree that each to their own, but come on ...

revlac, the problem with lithium forklift batteries is a lot to do with counter balance,  you NEED the weight, where one of lithiums " pro's " is actually to its detriment.. so unless specific for a special occasion , they will be rare...
I think it works !!
 
Davo99
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Posted: 07:22am 09 Feb 2022
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  bob.steel said  Davo you just don't get it .


Oh I get it allright!
you are one of those Fanbio lithium fanatics that won't have a thing said against them like they are your child or something.

  Quote  You are wrong with most of your comments


Pretty ironic given the rubbish and errors you have spouted.

  Quote   and its not worth my time to keep correcting you .


Bwahahaah!  Thank Christ for that!
There are a Lot of smart, educated and highly intelligent people on this board.
I do not consider you to be one of them and as such your opinions and advise hold no weight with me whatsoever.
You will be relived to know that I will not miss you not " correcting" me one bit although somehow, I am sure you will not be able to resist the compulsion to do so and grandstand in the process.

  Quote   However you can discharge them to zero volts if you want and I have done so and they recharge without damage . its just not what sensible people do as it can damage the cell if it happens frequently .


What???  
You can discharge them to zero without damage but don't do it because it can damage them....
And you reckon my comments are wrong? Yours are hypocritical and make no sense!

  Quote  You should stop posting this PARROTED anti-Lithium hearsay rubbish.




Said the fanboi whom won't have a thing said about his religious like fanaticism with Lipo.  

Please feel free to ignore every thing I say. Wouldn't want to waste your Valuable time although I do get a laugh out of your holier than thou BS.  
Edited 2022-02-09 17:25 by Davo99
 
Davo99
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Posted: 07:51am 09 Feb 2022
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  bob.steel said  
but its said if you get more than 3 years from Lead acid you are not using them.


Who said that load of crap? You? I have NEVER read that even once.

Funny, 2 different people I personally know ( apart from loads I have read testament from on the net)  have had LA Batteries for well over 10 Years. Some people I was talking to a fortnight ago were telling me the ones they currently have  are 14 Years old and the pack they had before than made it to 16.

It's ridiculous crap like this people make up which is typical of the Lipo fanboi compulsion to invent complete lies about LA to make their grandstanding about Lithium seem more compelling.
And you have the Gall to say other peoples comments need correcting? Bwahahah!!



It had dendrites and one cell shorted . If you know what you are doing you can get them back up and charging . Its about 8 years old now and still shows 90% capacity.

So these cells had failed Before they were even 8 years old and most people by your account whom are not of such superior knowledge as yourself,  which is most likley everyone else in the world, would have had to throw them away???
Now tell me about the 20 year longevity of Lipo again will you?

Oh, and now at 8 years old they are down to 90%... buy your account so I'd expect reality to be more like 50% at best.  Does not bode well for their future capacity does it?


  Quote   These are cheap . Cheaper than lead acid now.


Yep, there we go with that old chestnut of steaming BS again. Haven't we already had that False claim a page or so back and shown it to be a complete Lie? Yes, that's right, we did!!

Did you mean they are cheaper if you can't do basic Multiplication of the cost and then make up excuses to cover the lack of mathematical skills  or do you mean in like real money you have to pay for a similar capacity set of LA?

No, you can't mean that because that's just a moronic parroted claim that people say but can NEVER prove when the simple question " where can I buy these lithium batteries that are cheaper than LA?" is asked.  

There is always an excuse or some huffing and puffing but never a credible answer.    
 
Warpspeed
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Posted: 08:10am 09 Feb 2022
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The day that lithium beats lead on a Kwh per dollar basis, you will never see another lead battery in any new fork lift.
Piston powered fork lifts do just fine with massive cast iron counterweights.
Weight is not why lead is used in fork lifts, its COST.
Cheers,  Tony.
 
Davo99
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Posted: 08:13am 09 Feb 2022
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  noneyabussiness said  
but some people are so worried about going off grid because of myths like this, that they need to spends BIG dollars on the latest tech just to get some imaginary time / cycle life , because if its not x brand / type you won't get the cycles / life out of it... which is simply not true...


You are spot on there mate and I see it every day on an off grid forum I am on. People are paying CRAZY money like $30-50K for a solar? battery system because all the vested interests and useful idiots  carry on like we have seen here that only lipo can possibly work.

They seem to forget the many decades before lithium recently came along that people go on just fine with LA and it served peoples needs well.
The people that are using LA are always shouted down and made to look like idiots for not spending 5x more On Lithium to get twice the ( ESTIMATED but unproven) life span.

It's very much a conditioning and profit exercise by the industry with the support of those trying to justify their decisions in spending way too much on their system.

  Quote  revlac, the problem with lithium forklift batteries is a lot to do with counter balance,  you NEED the weight, where one of lithiums " pro's " is actually to its detriment.. so unless specific for a special occasion , they will be rare...


It would be interesting to get an idea of what percentage of Forks are being fitted with Lithium batteries now and what the bean counters position on them is whom have fleets and have run them against LA.
Does Industry find them worthwhile or are they for the majority sticking to LA?

If used lithium packs became as available as LA, that might be good but myself, I am yet to see any being offered for sale.
 
Revlac

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Posted: 09:38am 09 Feb 2022
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  Quote  I don't remember the brand, they were clear plastic cases, 200 amp hour each from memory. I was give about 40 of them , so just checked each out, got rid of the ones that had corroded terminals,


Thanks Pete,
Sounds Identical, was also free, The old man and I just had to pick them up.

  Quote  the problem with lithium forklift batteries is a lot to do with counter balance,  you NEED the weight, where one of lithiums " pro's " is actually to its detriment.. so unless specific for a special occasion , they will be rare...


I'm well aware of the counter balance, plenty of weight on the forklift at home, There are quite a few forklifts with outriggers/wheels that are out as far as the forks, pretty sure they are made for specialised shelving,  I did watch a doco a year ago, inside a car manufacturing plant, they had a fleet of driver-less forklifts, they might have used lithium I don't remember, Cost Doesn't matter, just add it to the price of the car.

I do agree though, I doubt they will be used in yard forklifts any time soon, for this reason you do need the weight.  
Cheers Aaron
Off The Grid
 
bob.steel
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Joined: 27/02/2020
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Posts: 188
Posted: 11:07am 09 Feb 2022
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  brucedownunder2 said  I would like to understand the working of the rechargeable li-ion battery pack ?

I understand ,by opening my flat-pack ,that the batteries are in plastic sealed packets.  There must be plates of metal inside ,plus cables ,I have not touched the sealed packets.

They are swelled from a previous owner ,who I do not know.

Could someone out there explain to me how these packets of rare earth or whatever is a mixture of whatever in there ,how they work ,please. I have no intension of opening them , would just like to understand the mechanical working of whats in there and how does the power ,when they are charged, travel .

its a fairly big unit , says 2500 watts and I've applied 48vdc ,it shows 81 watts into the unit ,don't know if this is charging(no indicators), or this 81 watts is consumed in the battery management system ?. no warm feeling on the packets, been on power for 1 hour.

Thanks
Bruce (change the topic heading and re-locate to another section ,if Solar is not appropriate..

thanks


Sorry to interfere here . To answer your original question
Go in to Facebook ,go to https://www.facebook.com/groups/271980786862023/
A page I run . Join up by answering the 1 question ,then go to the top right under "Files" and look for LFP facts . Read up there . Its on LFP not Lithium Ion.
They are different .

Also search on utube for "how Lithium Batteries work" There are many there that will help you understand

Daveo is a bit of a nutter who can't stop posting crap. Hess been everywhere and heard it all but never done it and can't stop shouting out his ignorance it seems.
.
Edited 2022-02-09 21:10 by bob.steel
 
bob.steel
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Posted: 09:27pm 12 Feb 2022
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  noneyabussiness said  " To each his own but its said if you get more than 3 years from Lead acid you are not using them. "

its comments like this that really peeve me off, one of the forklift batteries Im using is 3 and a half years old, as good as the day i recieved it, I pull a minimum 30 % out of it every night ( common to use 40-50) how is that " not using it " ?? I have nothing against li-ion , but some people are so worried about going off grid because of myths like this, that they need to spends BIG dollars on the latest tech just to get some imaginary time / cycle life , because if its not x brand / type you won't get the cycles / life out of it... which is simply not true... I do totally agree that each to their own, but come on ...


Look thats all good . Used at 30% lead acid does last.
I can use my LFP batteries down to 10 volts on a 12 volt battery so useable range is about 13.6 volts to 11 volts . On a graph that represents about 85 to 90 % of their capacity and they will last more than 10 years doing it that way.

What does that give me . Well for one I don't need to have 800 Amphours any more as 200 Amphours of LFP will do the job better. Obviously a lot less cost too.

I'm not saying toss yours out . I'm suggesting when they die you replace them with LFP. Contrary to popular hearsay you can parallel them with Lead acid and lead acid will benefit from that as LFP will take most of the work ,supplying current to the load and to the lead acids . There is no reason that will do damage to the LFP .

I had such a setup on my boat before the lead  acids finally gave out . I followed the doomsayers and left lead acid in to start my 6.354 Perkins diesel. When I tossed the lead and went wholly LFP what a difference . The starting voltage did not sag so it gave more power to the starter and a lot less amps.
Edited 2022-02-13 07:43 by bob.steel
 
bob.steel
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Posted: 09:51pm 12 Feb 2022
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  Warpspeed said  The day that lithium beats lead on a Kwh per dollar basis, you will never see another lead battery in any new fork lift.
Piston powered fork lifts do just fine with massive cast iron counterweights.
Weight is not why lead is used in fork lifts, its COST.


200Ah LFP @12v = $780 on Ebay delivered Australia wide free.Same in the States and I think they have a warehouse in Europe too.

What does a 200Ah lead acid equivalent forklift battery cost?

One outlasts the other by 4 times. No corrosion,no voltage sag,less weight.
Edited 2022-02-13 07:54 by bob.steel
 
Warpspeed
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Posted: 10:49pm 12 Feb 2022
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I don't think they make a 200Ah fork lift battery.  
The smallest fork lift cells I am aware of are around 340Ah. I believe the cost of those is around $2,500 for 24 cells (48v) delivered, the last time I looked.

If we refer all this back to a 12v battery:
Six of those 2v lead fork lift cells (12v) might be about $625 for 340Ah.
That works out to $1.83 per Ah (at 12v)

For your 200Ah LFP @ 12v = $780
That works out to $3.90 per Ah
That is actually very good.

Winstons are advertised at $1.85 per amp hour per cell.
At 12v four cells would be required.
So for Winstons $7.40 per AH (at 12v)

The whole thing revolves around expected lifetime.

Lead acids generally are expected to gradually lose capacity, although scrupulously and professionally maintained lead acid telephone exchange batteries have proven to last for fifty years or more.
If a home solar battery is hugely oversized, it can lose a very great deal of its initial rated capacity and still be perfectly usable.

While Lithium is a very much nicer battery in so very many ways, assuming its going to be totally reliable for ten or twenty years may be too optimistic.
If you read all the limitations, which if exceeded only once can lead to permanent damage if not outright failure is rather a worry.

I have had three cells go total dead short one by one over three years.  Coming up to year four now, and another cell could fail at any moment without warning.
That gets expensive...

Lead is far more rugged and will usually recover from an infrequent accident if its caught in time. Lithium is far more fragile.  The cells seem to be either perfect or totally dead, with nothing in between, at least that has been my own personal experience.

How can one cell suddenly go dead short in a series string of thirty ?  If it was through abuse, you would expect all thirty to suffer in a similar way.  My cells have never been thrashed or abused, but they keep dying suddenly one at a time and without warning.
Edited 2022-02-13 09:49 by Warpspeed
Cheers,  Tony.
 
Revlac

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Posted: 11:46pm 12 Feb 2022
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Used at 30% lead acid does last.
I can use my LFP batteries down to 10 volts on a 12 volt battery so useable range is about 13.6 volts to 11 volts . On a graph that represents about 85 to 90 % of their capacity


Yes, Correct but this and the marketing is always pointed to 12v systems for camping, power tools and some other equipment, going flat is not a big issue, as in camping, 4wd trips the 12v battery would be running fridges and accessories for however long, if it is flat by say 4:00AM (don't annoy other campers) just start the 4wd of geny in the morning and charge it abit.

This marketing is why people get a prickly cactus up there bum.  

Most inverters low voltage cut off is 11v some 10.5 per 12v battery, 44V cut off for a 48v system, any capacity left in a battery below that you Don't get.  

For an offgrid purpose the advertising of being able to run them to 90% DOD is Wrong, you should not get near that low and should avoid doing so, you need some headroom for bad weather, same for any off grid battery storage.
Cheers Aaron
Off The Grid
 
bob.steel
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Posted: 09:38am 14 Feb 2022
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  Revlac said  
Used at 30% lead acid does last.
I can use my LFP batteries down to 10 volts on a 12 volt battery so useable range is about 13.6 volts to 11 volts . On a graph that represents about 85 to 90 % of their capacity


Yes, Correct but this and the marketing is always pointed to 12v systems for camping, power tools and some other equipment, going flat is not a big issue, as in camping, 4wd trips the 12v battery would be running fridges and accessories for however long, if it is flat by say 4:00AM (don't annoy other campers) just start the 4wd of geny in the morning and charge it abit.

This marketing is why people get a prickly cactus up there bum.  

Most inverters low voltage cut off is 11v some 10.5 per 12v battery, 44V cut off for a 48v system, any capacity left in a battery below that you Don't get. Actually on my home power system I run mine between 50 and 54 volts only because thats most of the capacity anyway of LFP and the inverter will not let me set it lower than that . Its a MPPSolar Hybrid 5K

For an offgrid purpose the advertising of being able to run them to 90% DOD is Wrong, you should not get near that low and should avoid doing so, you need some headroom for bad weather, same for any off grid battery storage.


On 90 % DOD . No problem taking them down there if you go camping once a month or twice a year . The batteries won't notice it . Taking them daily down there is expected to halve their lifetime . So only 2500 cycles instead of 5000. That's still about 7 1/2 years if done daily.(And those results have been done and proved)
 
bob.steel
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Posted: 09:50am 14 Feb 2022
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  Warpspeed said  I don't think they make a 200Ah fork lift battery.  
The smallest fork lift cells I am aware of are around 340Ah. I believe the cost of those is around $2,500 for 24 cells (48v) delivered, the last time I looked.

If we refer all this back to a 12v battery:
Six of those 2v lead fork lift cells (12v) might be about $625 for 340Ah.
That works out to $1.83 per Ah (at 12v)

For your 200Ah LFP @ 12v = $780
That works out to $3.90 per Ah
That is actually very good.You only need 1/4 of the capacity with LFP though so 3.90/4= 98 cents comparison thats half of lead acid?.

Winstons are advertised at $1.85 per amp hour per cell.
At 12v four cells would be required.
So for Winstons $7.40 per AH (at 12v)Winstons and CALB are made in China too

The whole thing revolves around expected lifetime.,weight volume occupied and corrosion

Lead acids generally are expected to gradually lose capacity, although scrupulously and professionally maintained lead acid telephone exchange batteries have proven to last for fifty years or more. My old man was a PMG instrument technician and built exchanges in Northern Rhodesia and Sydney. He would disagree with you as I do .Theiir oltage was 60-70 volts if I remember correctly but only when the line was active . 9 volts or something when idle.
If a home solar battery is hugely oversized, it can lose a very great deal of its initial rated capacity and still be perfectly usable.

While Lithium is a very much nicer battery in so very many ways, assuming its going to be totally reliable for ten or twenty years may be too optimistic.
If you read all the limitations, which if exceeded only onceThat's just wrong Tony and Ill prove it to you if you wish . If I can get another edit in here I'll bring a screed over on overcharging. If not it will be lower down mate can lead to permanent damage if not outright failure is rather a worry.

I have had three cells go total dead short one by one over three years.  Coming up to year four now, and another cell could fail at any moment without warning.
That gets expensive...You said that and I'm wondering who you bought your cells from? Its a punt because you will never know what use they have had before you. They are tarted up but the plates can be just screwed if they have been abused . Its a risk we all take buying from Ali-Express. I've lost one cell. That's the one I showed you the plates of elsewhere.On my home solar I ordered 16 and then another 4 just to be sure I have spares . Have not had to use them yet in 3 years.

Lead is far more rugged and will usually recover from an infrequent accident if its caught in time. Lithium is far more fragile.  The cells seem to be either perfect or totally dead, with nothing in between, at least that has been my own personal experience.

How can one cell suddenly go dead short in a series string of thirty ?  If it was through abuse, you would expect all thirty to suffer in a similar way.  My cells have never been thrashed or abused, but they keep dying suddenly one at a time and without warning.
Its to do with whatever the previous use was . Do they show any voltage at all? Try the dendrite treatment ,40 volts as high a current as you can put out and 5 half second pulses of only. Then put on a charger /lab supply with 3.65v set volts and current down at about 1 amp and leave.See what you have in 24 hours.If its a dendrite short they show some voltage because there is some plate volume active either side but if you have left them too long they can completely discharge.
Overcharge_Overdischarge of LiFePo4 cells (1).pdf

Its heavy going and only looks at 18650 cells but the chemistry is identical in all cells up to 320Ah.
Edited 2022-02-14 20:11 by bob.steel
 
Revlac

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Posted: 11:04pm 14 Feb 2022
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Bob, I have a 4048HS (since 2015 one easy repair but still going) and A 5048MS Acquired later, I know the inverters,
I have run lithium (off grid) for over 5 years, Yes you could take them down to 90% DOD, in a properly sized system it should not get down that far, certainly not on a daily basis, sadly people are sold the idea that they can get away with an under size battery, and some off grid attempts  have failed horribly.
I see you had 100Ah and have upgraded to 300Ah, much better, no worries about DOD.
Cheers Aaron
Off The Grid
 
bob.steel
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Posted: 02:59am 15 Feb 2022
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  Revlac said  Bob, I have a 4048HS (since 2015 one easy repair but still going) and A 5048MS Acquired later, I know the inverters,
I have run lithium (off grid) for over 5 years, Yes you could take them down to 90% DOD, in a properly sized system it should not get down that far, certainly not on a daily basis, sadly people are sold the idea that they can get away with an under size battery, and some off grid attempts  have failed horribly.
I see you had 100Ah and have upgraded to 300Ah, much better, no worries about DOD.


Yes what I have is a MPP HV2 5048 same as this .They recommended a 300Ah battery but I didn't want to commit that much until I checked it out.

Home MPPSolar  System

really happy with it
Edited 2022-02-15 13:01 by bob.steel
 
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